Try browsing to C:\Users\[USERNAME]\Documents\My Games\Ironclad Games\Sins of a Solar Empire Rebellion\Setting and deleting the rebellion.user.setting file. Does the game start normally after that?
Another option could be to run as administrator. Particularly if you are running this through steam and have started steam as administrator.
If that Doesn't work try using the compatibility option to run as windows 8. Oddly enough that works 9/10 times for me.
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